We consider a family of thermodynamic models such that the energy density can be expressed as an asymptotic expansion in the scale formal parameter and whose terms are suitable functions of the volume density. We examine the possibility to construct solutions for the Maxwell thermodynamic relations relying on their symmetry properties and deduce the critical properties implied in terms of the the dynamics of coexistence curves in the space of thermodynamic variables.
|Number of pages
|Journal of Physics A: Mathematical and Theoretical
|Early online date
|9 Sept 2021
|Published - 8 Oct 2021